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"Mr. Pitiful" was the first single to be released from Unfamiliar Faces on October 7, 2007. It was also released as a free "Single of the Week" on the iTunes Music Store in Canada and Australia. "Mr. Pitiful" is used in commercials for the Apple iPhone 3GS. It is featured in the movie and also appears on the soundtrack for the film, I Love You, Man.

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