Hands down my favourite. And it's an orchestral. You don't need some big budget singer to make a great Bond theme!
2. The James Bond Theme
Okay, I suppose this really shouldn't go on the list, but it was the theme for Dr. No, so blah. The essential :D
3. You Know My Name
I'm probably going to get chastised for having this one so high on my list, but according to my iPod, I've listened to it over 700 times, so Cornell must be doing something right. This was the song to the first James Bond film I fell in love with, and on top of that, it's a really great song. (one consistency - I tend to like the themes done by David Arnold or John Barry. :D)
4. A View to a Kill
I'm ashamed to say I haven't actually seen the film (I haven't seen a lot of the Bond films, actually), but I adore this track.
5. Tomorrow Never Dies
For some reason, I'm magnetized to this track. It kind of exudes that whole dark spy motif.
6. Nobody Does It Better